No. Will not be bootable anymore. GPT requires UEFI boot. Migration from MBR/BIOS boot to UEFI boot is not possible. =>
How to convert MBR Hard Disk to GPT Hard Disk
With a recent Windows install it would be most easy to clear the disk, convert to GPT, and install Windows in UEFI mode.
With a very customized Windows one COULD (no warranty, just thinking loudly):
* Create a backup of C:
* Clear the disk.
* Convert to GPT.
* Start installing Windows in UEFI mode.
* Cancel the install when Windows starts copying files. In this stage of the install the GPT/EFI infrastructure is already created as needed.
* Remove C:.
* Restore the backup of C:.